Intermolecular Forces

Learning Objectives

  • the relative strengths of bonds (covalent bonding, dispersion forces, dipole-dipole attraction and hydrogen bonding) and evidence and factors that determine bond strength including explanations for the floating of ice and expansion of water at higher temperatures.

Summary Notes

INTRAmolecular vs INTERmolecular forces

Intramolecular forces are the forces between covalent bonding within molecules.

Intermolecular forces are the forces of attraction between molecules that hold molecules together.

Weakest Intermolecular Force: Dispersion

  • Present in all molecules

  • Depends on 'instantaneous dipole'

  • Forces of attraction are between the instantaneous positive end of one molecule and the negative end of another molecule.


Stronger Intermolecular Force: Dipole-Dipole

  • Present in polar molecules

  • Permanent dipole

  • Forces of attraction are between positive end of one molecule and negative end of another

Strongest Intermolecular Force: Hydrogen Bonding

  • Hydrogen bonding is the force of attraction between the hydrogen atom on one molecule and the fluorine, oxygen or nitrogen atom on another molecule.


Video to help build your understanding

*Note: Van der Waal/ London forces which are mentioned in this video are the same as 'dispersion' forces

Practice Material